Synthetic Studies of the Yunnaneic Acids
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Synthetic Studies of the Yunnaneic Acids

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1 pages 2013

About This Book

The total syntheses of yunnaneic acid C, yunnaneic acid D, and rufescenolide are described. The highly substituted bicyclic cores of these molecules were synthesized in a single step via a oxidative dearomatization/Diels-Alder cascade sequence from simple precursors. Dimerization studies towards yunnaneic acid A and yunnaneic acid B are also described, which resulted in the synthesis of several novel, non-natural structures.

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