Thiocarbonyl and related complexes of rhodium(I) and rhodium
Thiocarbonyl and related complexes of rhodium(I) and rhodium(III)
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Summary
The bulk of work described in this thesis concerns thiocarbonyl complexes of rhodium. A much smaller section is devoted to carbonyl complexes of rhodium.
Chapter I commences with a review of chemistry of thiocarbonyl compounds. Chapter II deals with preparation and characterisation of cationic complexes of rhodium(1), [Rh(CS)L3]+ and [Rh(CS)L4]+ (L = phosphine donor ligand). These complexes were studied by i.r. and phosphorous-31 n.m.r. spectroscopy.
Preparation of neutral thoicarbonyl complexes, RhX(CS)L2 and RhX3(CS)L2 (X = anionic ligand , L = phosphine ligand) is reported in chapter III. These complexes have been studied by i.r, phosphorous-31 and carbon-13 n.m.r. spectroscopy. The reactions of RhX(CS)L2 with tetracyanoethylene and sulphur dioxide have also been investigated.
Chapter IV and V contain the results of crystal structure determination on a representative four and five coordinate rhodium(1) thiocarbonyl and carbonyl compounds. The last chapter describes the experimental methods used in the course of this research.
The bulk of work described in this thesis concerns thiocarbonyl complexes of rhodium. A much smaller section is devoted to carbonyl complexes of rhodium.
Chapter I commences with a review of chemistry of thiocarbonyl compounds. Chapter II deals with preparation and characterisation of cationic complexes of rhodium(1), [Rh(CS)L3]+ and [Rh(CS)L4]+ (L = phosphine donor ligand). These complexes were studied by i.r. and phosphorous-31 n.m.r. spectroscopy.
Preparation of neutral thoicarbonyl complexes, RhX(CS)L2 and RhX3(CS)L2 (X = anionic ligand , L = phosphine ligand) is reported in chapter III. These complexes have been studied by i.r, phosphorous-31 and carbon-13 n.m.r. spectroscopy. The reactions of RhX(CS)L2 with tetracyanoethylene and sulphur dioxide have also been investigated.
Chapter IV and V contain the results of crystal structure determination on a representative four and five coordinate rhodium(1) thiocarbonyl and carbonyl compounds. The last chapter describes the experimental methods used in the course of this research.
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